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Oxygenates by Homologation or CO Hydrogenation with Metal Complexes by A. Braca

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Item specifics

Condition
Brand New: A new, unread, unused book in perfect condition with no missing or damaged pages. See all condition definitionsopens in a new window or tab
ISBN-13
9780792326281
Book Title
Oxygenates by Homologation or CO Hydrogenation with Metal Complex
ISBN
9780792326281
Publication Year
1993
Type
Textbook
Format
Hardcover
Language
English
Author
Giuseppe Braca
Item Length
9in
Publisher
Springer Netherlands
Genre
Technology & Engineering, Science
Topic
Chemistry / Physical & Theoretical, Industrial Health & Safety, Chemical & Biochemical, Chemistry / Inorganic, Chemistry / Organic, Chemistry / General
Item Width
6in
Item Weight
40.9 Oz
Number of Pages
Xvi, 227 Pages

About this product

Product Information

Born and initially developed in various industrial laboratories, mainly in U.S.A. and Gennany, homogeneous phase catalytic carbon monoxide hydrogenation and alcohols and their derivatives carbonylation and homologation, have generally been considered and reviewed separately in the course of their 40 years history without concern for common aspects in the chemical transfonnations and in catalysis. Thanks to researchers of Japanese companies participating in the National C 1 Chemistry Project (1980-1987) the scientific and technical approaches in this field have been unified and applied in parallel, in the light of some common aspects of the chemical reactions and mechanisms. Now, at a moment when research seems becahned, a general presentation and discussion of the most recent topics might be an useful basis for further development of this chemistry. To delimit and simplify the discussion of the chemical aspects and the nature of the catalysts involved, the present review is limited to reactions employing homogeneous metal complexes for the direct conversion of syngas to oxygenates and to the hydrocarbonylation of these last to homologous derivatives. Since the previous practically contemporary reviews by Dombek [in Adv. Organomet. Chern. (1983)] on CO hydrogenation and by the present authors [in Asp.Homog.Catal.(Reidel Pu.l984)] on alcohol homologation fully cover the literature up to 1982, here we mainly refer to work done after 1982, and consider the cited reviews as covering the historical development of research in the 1940- 1980 period.

Product Identifiers

Publisher
Springer Netherlands
ISBN-10
0792326288
ISBN-13
9780792326281
eBay Product ID (ePID)
308282

Product Key Features

Author
Giuseppe Braca
Format
Hardcover
Language
English
Topic
Chemistry / Physical & Theoretical, Industrial Health & Safety, Chemical & Biochemical, Chemistry / Inorganic, Chemistry / Organic, Chemistry / General
Publication Year
1993
Type
Textbook
Genre
Technology & Engineering, Science
Number of Pages
Xvi, 227 Pages

Dimensions

Item Length
9in
Item Width
6in
Item Weight
40.9 Oz

Additional Product Features

Series Volume Number
16
Number of Volumes
1 Vol.
Lc Classification Number
Qd410-412.5
Publication Name
Oxygenates by Homologation or Co Hydrogenation with Metal Complexes
Table of Content
Monoalcohols, Glycols, and their Ethers and Esters by CO Hydrogenation.- Department of Chemistry and Industrial Chemistry, University of Pisa, ITALY.- 1 Introduction.- 2 Cobalt catalysts.- 3 Ruthenium Catalysts.- 4 Rhodium catalysts.- 5 Other catalysts.- 6 Reaction mechanism.- 7 Industrial process development.- 8 References.- Alcohols and Derivatives by Homologation with Syn Gas.- Department of Chemistry and Industrial Chemistry, University of Pisa (ITALY).- 1 Introduction.- 2 Hydrocarbonylation of alcohols.- 3 Hydrocarbonylation of aliphatic ethers.- 4 Hydrocarbonylation of carboxylic acid esters.- 5 Homologation of acetic acid in the presence of ruthenium/iodide or rhodium/iodide catalysts.- 6 Homologation of methyl halides.- 7 Reactiom mechanism.- 8 Industrial processes development.- 9 References.- Hydrocarbonylation of aldehydes and their derivatives.- SNAM PROGETTI S.p.A. S.Donato Milanese (ITALY).- 1 Introduction.- 2 Hydroformylation of formaldehyde to glycol aldehyde.- 3 Hydrocarbonylation of formaldehyde to ethylene glycol.- 4 Hydrocarbonylation of formaldehyde to acetaldehyde and/or ethanol.- 5 Hydrocarbonylation of formaldehyde to higher oxygenated products.- 6 Hydrocarbonylation of higher aldehydes.- 7 Conclusions.- 8 References.
Copyright Date
1994
Lccn
93-023650
Dewey Decimal
547.03104593
Intended Audience
Scholarly & Professional
Series
Catalysis by Metal Complexes Ser.
Dewey Edition
20
Illustrated
Yes

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